In this study researchers from the Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO1), the Laboratory of fundamental Mechanisms in Bioenergetics (LMB/SB2SM) and from the Institut des sciences chimiques de Rennes (ISCR2) report a strategy to attach methylimidazolium fragments as ionic liquid units on an established iron porphyrin catalyst for the selective reduction of CO2 to CO. Importantly, they found that the tetra-methylimidazolium containing porphyrin exhibits an exalted electrocatalytic activity at low overpotential in water precluding the need for an external proton donor.
|
Le catalyseur © Philipp Gotico/CEA
|
[1] CNRS/Université Paris-Sud/Paris-Saclay
[2] CNRS/INSA Rennes/ENSC Rennes/Université Rennes 1